乙丙嵌段共聚物相对分子质量及链结构对PP/EPR共混体系结构与性能的影响

设计合成了一系列不同相对分子质量和乙烯平均序列长度的乙丙嵌段共聚物（EP），并将其作为聚丙烯（PP）/二元乙丙橡胶（EPR）共混体系的增容剂，考察了EP用量、相对分子质量及乙烯平均序列长度对共混体系性能及分散相形态演变的影响。结果表明，EP增容PP/EPR体系时存在最佳添加量，少量EP的加入可有效提高PP/EPR共混体系的抗冲击性能，并对分散相尺寸及形态起到良好的调控作用；同时，EP的相对分子质量越大对共混体系的冲击性能提高越明显，EP的组成与EPR越接近，对共混体系的增容效果越明显。     

A novel methodology for evaluating wear behavior of rubber composites under combination of sliding and rolling conditions

The wear behavior of tire tread rubber composites has attracted widespread attention of researcher duo to its serious environmental pollution and high frequency of occurrence for a long time. Herein, a new test method is developed, an improved Akron friction testing machine on a laboratory scale was utilized to estimate the wear loss and mechanism of the rubber composites under rolling and sliding coupling condition. The results indicated that the wear loss quickly increases with the increase of the relative sliding velocity. The main wear mechanism, including adhesive, thermofatigue, tear and curl wear, was governed by the thermal deposition of the worn surface. Scanning electron microscope analysis showed thermal decomposition tear region gradually expanded on the worn surface by increasing relative sliding velocity. The heat distribution numerical analysis supported the experimental results, which confirmed that the heat distribution of the worn surface is entirely consistent with the distribution of the thermal decomposition tear region.     

改性碱式氯化镁晶须/丁苯橡胶复合材料制备与性能研究

以工业活性轻烧氧化镁粉和盐酸为原料,采用水溶液法制备了碱式氯化镁晶须,继而采用硅烷偶联剂对碱式氯化镁晶须进行改性,然后将其与丁苯橡胶混炼得到改性碱式氯化镁晶须/丁苯橡胶复合材料,研究了改性碱式氯化镁晶须对丁苯橡胶力学性能及热学性能的影响。结果表明：采用水溶液法制备得到的碱式氯化镁晶须结构为Mg₂（OH）₃Cl·4H₂O,呈微细纤维状,分布较均匀,长径比大于20;改性碱式氯化镁晶须的加入,可以改善丁苯橡胶的机械强度和阻燃性能。     

聚酯类增塑剂的合成与应用研究进展

综述了国内外聚酯增塑剂的合成及应用的最新研究进展，重点介绍了超支化、生物基、石油基聚酯增塑剂的合成与制备方法以及不同类型聚酯增塑剂在聚氯乙烯(PVC)、淀粉、聚乳酸、聚氨酯弹性体与橡胶制品中的最新应用研究进展；并对聚酯增塑剂未来发展方向做了展望。     

不同硬度PTMG型CPUE与硫化橡胶的性能对比研究

通过改变硬段含量、扩链系数等制备了几种不同硬度的四氢呋喃均聚醚(PTMG)浇注型聚氨酯弹性体(CPUE),讨论了PTMG型CPUE与硫化橡胶(VR)的物理机械性能、拉伸应力应变行为以及动态力学性能的区别。结果表明,随CPUE硬度的提高,材料的刚性增强,力学性能是低硬度VR的数倍。通过对CPUE硬度的调节,可以使之兼具聚氨酯和橡胶的优良性能。在玻璃态温度下CPUE的储能模量随硬度的减小而降低,但都高于VR,而且CPUE的硬度越大,二者相差越大,温度越低,相差也越大;在室温以上温度范围内,CPUE具有比VR更小的力学损耗。     

Study of using a multi-touch tabletop technology to facilitate collaboration,interaction, and awareness in co-located environment

This study aimed to evaluate how differently co-located users perform and interact while solving problems by using existing and newly developed interaction mechanisms of a multi-touch tabletop system on a large-size tabletop display. Furthermore, this study aimed to investigate users’ perceived situation awareness due to the system. This study conducted one experiment and introduced three newly developed interaction mechanisms: two-way rubber band, drag-and-response, and centre collection area. Two-way rubber band enables users not only to send but also to request digital objects. Drag-and-response allows users to accept or to reject digital objects sent by others; therefore, it eliminates conflicting situations and interference. Centre collection area stores, organises, and manages shared digital resources on a surface of a tabletop display, so that users have an overall picture of available resources. This paper discusses results of an experiment, research findings, and implications along with conclusions and several suggestions for future development and research.     

橡塑往复密封性能参数数值求解流程与物理模型探讨

橡塑往复密封的密封寿命通常是通过膜厚、承载力、泄漏率、磨损率等参数以表征。为获取上述参数,佐治亚大学SALANT提出橡塑往复密封模型建立和数值计算求解流程。为更好地理解与应用该方法,从橡塑往复密封物理结构、数值求解流程、Reynolds方程建立、方程约束边界建立、GW接触模型建立、力载平衡等6个方面系统地分析其特点与不完备之处,并从6个方面探讨数值求解流程和数值模拟的修正方法;提出密封模型修正方法,给出修正后密封数值求解流程,使得计算结果更好地与实际工作性能相吻合,并能较好地揭示密封机制。     

我国聚丁二烯橡胶生产技术进展及市场分析

从生产工艺、新产品开发以及装置设备等方面概述了我国聚丁二烯橡胶生产技术的研究进展,并分析了我国聚丁二烯橡胶的市场情况。2019年我国聚丁二烯橡胶的生产能力为161.5万t/a,消费量为121.0万t,预计2024年消费量将达到约135.0万t。指出了我国聚丁二烯橡胶行业今后的发展趋势。     

自愈合橡胶材料研究进展

具有自感知、自诊断、自愈合功能的智能聚合物材料是高分子科学领域的前沿材料之一。介绍了自愈合橡胶材料的自愈合机理,综述了自愈合橡胶材料的分类、特性和发展概况,展望了其应用及发展前景。     

Investigation of the Sharkskin melt instability using optical Fourier analysis

An optical method allowing the characterization of melt flow instabilities typically occurring during an extrusion process of polymers and polymer compounds is presented. It is based on a camera-acquired image of the extruded compound with a reference length scale. Application of image processing and transformation of the calibrated image to the frequency domain yields the magnitude spectrum of the instability. The effectiveness of the before mentioned approach is shown on Styrene-butadiene rubber (SBR) compounds, covering a wide range of silica filler content, extruded through a Göttfert capillary rheometer. The results of the image-based analysis are compared with the results from the sharkskin option, a series of highly sensitive pressure transducers installed inside the rheometer. A simplified version of the code used to produce the optical analysis results is included as supplementary material. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48806.